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The order of titration can indeed matter when analyzing the titratable acidity and salt content of a solution containing ketchup.

Typically, when performing these analyses, it is recommended to first determine the titratable acidity using a base titration, such as titrating with NaOH solution. This is because the acidity is usually expressed as a percentage of acid content, and titrating with a base allows for the measurement of the amount of acid present in the sample.

Once the titratable acidity has been determined, the second step involves determining the salt content. This is commonly done through a precipitation reaction using silver nitrate (AgNO3) to precipitate chloride ions from the salt. The amount of chloride ions present corresponds to the salt content in the sample.

Therefore, the recommended order of analysis would be:

  1. Titratable acidity determination: Titrate the ketchup sample with NaOH solution to determine the acid content.
  2. Salt analysis: Perform a precipitation reaction with AgNO3 to determine the salt content based on the chloride ion concentration.

By following this order, you can obtain accurate measurements of both the titratable acidity and the salt content of the ketchup sample.

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