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Hydrogen peroxide (H₂O₂) does not naturally exist in its water-free form due to its highly reactive nature. Hydrogen peroxide is a powerful oxidizer and can readily undergo decomposition, releasing oxygen gas (O₂) and water (H₂O).

In the presence of water, hydrogen peroxide can form hydrogen bonds with water molecules, stabilizing its structure and reducing its reactivity. The hydrogen bonds help to maintain the stability of hydrogen peroxide by preventing or slowing down its decomposition. Water acts as a solvent for hydrogen peroxide, providing a medium where it can exist without rapidly breaking down.

In its pure, anhydrous form, hydrogen peroxide can be highly unstable and prone to decomposition. It can react vigorously with various substances, including metals, organic compounds, and other reactive chemicals. To store and handle hydrogen peroxide safely, it is typically diluted with water, reducing its concentration and reactivity.

Therefore, the presence of water is essential to maintain the stability and prevent the rapid decomposition of hydrogen peroxide, which is why it does not naturally exist in its water-free form.

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