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Osmotic pressure is the pressure exerted by a solvent as it moves across a semipermeable membrane to equalize the concentration of solute on both sides of the membrane. It is a colligative property, which means it depends on the concentration of the solute particles rather than the specific identity of the solute.

The osmotic pressure of a solution is directly proportional to the concentration of the solute. This relationship is described by the van't Hoff equation:

π = i * C * R * T

Where:

  • π represents osmotic pressure,
  • i is the van't Hoff factor, which accounts for the degree of dissociation or association of the solute particles (e.g., the number of ions produced when an ionic compound dissolves),
  • C is the molar concentration of the solute in the solution,
  • R is the ideal gas constant,
  • T is the absolute temperature.

According to the equation, as the concentration of the solute (C) increases, the osmotic pressure (π) of the solution also increases. This relationship is consistent with the fact that a higher concentration of solute particles creates a larger concentration gradient across the semipermeable membrane, resulting in a greater tendency for solvent molecules to move from the region of lower solute concentration to the region of higher solute concentration. Consequently, a higher osmotic pressure is required to prevent the net flow of solvent molecules and establish equilibrium.

In summary, the concentration of the solute directly affects the osmotic pressure of a solution. Higher solute concentrations lead to higher osmotic pressures.

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