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To solve this problem, we can use the combined gas law, which relates the initial and final states of a gas sample. The combined gas law equation is as follows:

(P1 * V1) / (T1) = (P2 * V2) / (T2)

Where: P1 = Initial pressure (unknown) V1 = Initial volume T1 = Initial temperature P2 = Final pressure V2 = Final volume T2 = Final temperature

Given: V1 = 436 mL T1 = 24 °C = 24 + 273.15 K = 297.15 K V2 = 612 mL T2 = 97 °C = 97 + 273.15 K = 370.15 K P2 = 526 mm Hg

Substituting these values into the combined gas law equation, we have:

(P1 * 436 mL) / (297.15 K) = (526 mm Hg * 612 mL) / (370.15 K)

Now, we can solve for P1 by rearranging the equation:

P1 = (526 mm Hg * 612 mL * 297.15 K) / (436 mL * 370.15 K)

P1 ≈ 361.6 mm Hg

Therefore, the original pressure is approximately 361.6 mm Hg.

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