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To solve this problem, you can use the ideal gas law equation:

PV = nRT

Where: P is the pressure V is the volume (kept constant in this case) n is the number of moles of gas (assumed to be constant) R is the ideal gas constant (0.0821 L·atm/(mol·K) or 8.314 J/(mol·K)) T is the temperature in Kelvin

Since the volume is kept constant, the equation simplifies to:

P₁/T₁ = P₂/T₂

Where: P₁ is the initial pressure T₁ is the initial temperature P₂ is the final pressure (what we want to find) T₂ is the final temperature

Now we can plug in the given values:

P₁ = 780.0 mm Hg T₁ = 323.0 K T₂ = 283.15 K (cooled temperature) P₂ = ? (what we want to find)

P₁/T₁ = P₂/T₂

Solving for P₂:

P₂ = (P₁ * T₂) / T₁

P₂ = (780.0 mm Hg * 283.15 K) / 323.0 K

Calculating this expression gives:

P₂ ≈ 683.75 mm Hg

Therefore, the final pressure would be approximately 683.75 mm Hg.

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