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When working with diatomic elements in chemistry problems, whether to use the molar mass or atomic mass depends on the context and the specific information given in the problem. Let's clarify the terms:

  1. Atomic Mass: This refers to the average mass of one atom of an element, expressed in atomic mass units (u) or grams per mole (g/mol). Atomic masses are listed on the periodic table.

  2. Molar Mass: This is the mass of one mole of a substance, expressed in grams per mole (g/mol). The molar mass of a diatomic element will be twice its atomic mass because one mole of a diatomic element contains two atoms.

To determine whether to use molar mass or atomic mass in a problem involving diatomic elements, consider the following scenarios:

  1. Calculating the mass of a sample: If you are given the number of moles or the mass of a sample of a diatomic element, you should use the molar mass to convert between moles and grams. Multiply the given quantity by the molar mass to obtain the desired unit (grams or moles).

  2. Calculating the number of atoms or molecules: If you need to determine the number of atoms or molecules of a diatomic element, you can use Avogadro's number (6.022 × 10^23) in conjunction with either the atomic mass or the molar mass. Remember that one mole of a diatomic element contains 6.022 × 10^23 molecules (or atoms), so you can use the conversion factor to relate the given quantity to the desired unit.

  3. Reacting masses in chemical reactions: When balancing chemical equations or calculating the quantities of reactants and products, you typically use the molar mass of the diatomic element to relate the number of moles of one substance to another.

In summary, if you need to convert between moles and grams, use the molar mass. If you want to determine the number of atoms or molecules, you can use either the atomic mass or the molar mass, along with Avogadro's number. The specific problem details will guide you on which approach to use.

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