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In chemistry, there is a distinction between the terms "atomic weight" and "mass number." While both are related to the mass of atoms, they represent different concepts:

  1. Atomic Weight (or Atomic Mass): Atomic weight, also referred to as atomic mass, is a weighted average of the masses of the isotopes of an element, taking into account their natural abundance. It is expressed in atomic mass units (u) or grams per mole (g/mol). Atomic weights are listed on the periodic table and provide a standard value for the average mass of an atom of a particular element.

The atomic weight considers the relative abundance of each isotope of an element in nature. Since different isotopes have different masses due to the varying number of neutrons, the atomic weight is a weighted average that accounts for the different isotopic compositions found in nature. It provides a useful reference for calculations involving elements and compounds.

  1. Mass Number: Mass number, on the other hand, is a whole number representing the sum of the protons and neutrons in an atomic nucleus. It is specific to a particular isotope of an element. The mass number is used to identify and distinguish different isotopes of an element.

The mass number is an integer value that helps determine the mass and stability of a specific isotope. It is commonly written as a superscript to the left of the element's symbol (e.g., ^12C, ^16O), indicating the total number of nucleons (protons plus neutrons) in that isotope's nucleus.

To address your question about why both terms exist, it's because they serve different purposes and provide distinct information. The atomic weight represents the average mass of all the naturally occurring isotopes of an element, accounting for their relative abundance, while the mass number specifies the mass of a particular isotope.

The existence of both terms allows for a more comprehensive understanding of the mass properties of atoms and isotopes. The atomic weight provides a convenient standard for general calculations and comparisons, while the mass number allows for precise identification and differentiation of specific isotopes within an element.

In summary, the distinction between atomic weight and mass number is important because they convey different information about the mass of atoms. Atomic weight is an average mass considering the isotopic distribution, while mass number represents the mass of a specific isotope.

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